The synthesis of High Consistency Rubber (HCR) is a meticulously controlled process that begins with blending polymethyl siloxane, a type of silicone rubber, with various vulcanizing agents and fillers. These components are blended in specific proportions to achieve the final product’s desired physical and chemical properties. This blending process takes place in a controlled environment to ensure homogeneity.
The mixed compound then undergoes a process known as milling, which refines the mixture’s consistency and eliminates entrapped air, ensuring the integrity and uniformity of the material. The critical phase of vulcanization or curing follows, wherein the material is subjected to heat and pressure, causing cross-linking of the polymer chains, which gives the material its characteristic elasticity and resilience.
The result is a high-consistency rubber that exhibits superior durability, resistance to environmental stressors, and versatility for many applications. The entire process is closely monitored and controlled to meet stringent quality standards.
In contrast to most Liquid Silicone Rubber (LSR) and Room-Temperature-Vulcanizing (RTV) materials that can be found readily in a pre-compounded system, HCR elastomers are generally formulated outside of the main polymer suppliers and need to be mixed together with other ingredients to create a usable seal and gasket material.
The primary ingredient in the formula for Silicone Elastomers is the polymer. Various base materials are used, which means that a lot of compounding has gone into these materials before they ever meet a custom mixer. These polymers come in a range of product lines covering a wide range of material hardness. The primary type to be used is a Vinyl Methyl Silicone, or VMQ, material, which is a Silicone Elastomer that has been modified to have vinyl groups on the polymer backbone. This modification allows for additional crosslinking and enables the silicone to be easily cured as it adds double bond sites to the material.
Fillers are the next major component of an HCR material. Similar to organic rubber, the purpose of these fillers is to add tensile and tear strength to the elastomer, as well as to raise the hardness of the material. Fume-treated silica is typically used because it has a tiny particle size, and treating the silica in this way helps it to better disperse in the elastomer.
A heat stabilizer is an ingredient that helps to protect the polymer backbone from being weakened by heat. These are usually some form of a metal oxide, such as Magnesium Oxide. Many seal materials for silicone are colored either a red or a brown shade because these use the Red Iron Oxide pigment.
When it comes to curing HCR material, peroxide is typically the curing agent of choice. The peroxide bond gets cleaved apart as the energy created from the polymer’s exposure to high temperatures creates crosslinks. This process attacks the vinyl double bonds and incorporates the peroxide so none is left behind.
Pigments are also part of the HCR formula. The most common pigment is the Red Iron Oxide pigment, but just about any standard color option is available and can also be blended together to create custom colors.